Sterically directed, site-preferential selenization of discrete copper sulfide nanoclusters
Site-preferential selenization of [Cu 12 S 6 ] nanoclusters arises from differentiated steric environments of apical and equatorial sites. This phenomenon is observed by X-ray crystallography and VT-NMR spectroscopy, and is supported by DFT calculations.
Authors
- Michael J. Trenerry (ORCID: https://orcid.org/0000-0003-1606-348X)
- Alex Lovstedt (ORCID: https://orcid.org/0000-0001-5812-1858)
- Jan-Niklas Boyn (ORCID: https://orcid.org/0000-0002-6240-3759)
- Gwendolyn A. Bailey (ORCID: https://orcid.org/0000-0002-6636-4128)
- Lauren E. Way
- Eryck García Labarca
Institutions
- University of Minnesota (US)
- Twin Cities Orthopedics (US)
Publication Details
- Journal
- Journal of Materials Chemistry A
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ta05259a
- Primary Topic
- Nanocluster Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00