Ru-catalyzed deoxydehydration (DODH) with hydrazine

A novel method for the deoxydehydration (DODH) of diols to alkenes has been developed by using hydrazine as a reductant <i>via</i> HOME (hydrazone as an organometallic equivalent) chemistry catalyzed by Ru-PNP complexes. This process avoids harsh reaction conditions, minimizes waste, and can be applied to a variety of diol compounds.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc04813c
Primary Topic
Asymmetric Hydrogenation and Catalysis
Type
article
Field-Weighted Citation Impact
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article

Ru-catalyzed deoxydehydration (DODH) with hydrazine

Siyi Luo, Ruofei Cheng, Zihang Qiu, Chenchen Li
Chemical Communications
Asymmetric Hydrogenation and Catalysis
article

Ru-catalyzed deoxydehydration (DODH) with hydrazine

Siyi Luo, Ruofei Cheng, Zihang Qiu, Chenchen Li
article en

Abstract

A novel method for the deoxydehydration (DODH) of diols to alkenes has been developed by using hydrazine as a reductant <i>via</i> HOME (hydrazone as an organometallic equivalent) chemistry catalyzed by Ru-PNP complexes. This process avoids harsh reaction conditions, minimizes waste, and can be applied to a variety of diol compounds.

Chemical CommunicationsVol. 61(81)
Centre in Green Chemistry and Catalysis (CA)
Openalex Percentile: Top 80%
Asymmetric Hydrogenation and Catalysis
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