Direct C(sp <sup>3</sup> )–H chloromethylation through CH <sub>2</sub> Cl <sub>2</sub> activation using non-thermal plasma
Catalyst-free chloromethylation of alkanes is achieved via non-thermal plasma activation of CH 2 Cl 2 under ambient conditions. A 30% yield of chlorinated products from cyclohexane is obtained in 60 s. A radical mechanism has been proposed.
Authors
- Gabriel Morand (ORCID: https://orcid.org/0000-0001-9832-5302)
- Louis Fensterbank (ORCID: https://orcid.org/0000-0003-0001-7120)
- Stéphanie Ognier (ORCID: https://orcid.org/0000-0002-0184-2336)
- Michaël Tatoulian (ORCID: https://orcid.org/0000-0002-1829-3249)
- Alain Favre‐Réguillon (ORCID: https://orcid.org/0000-0001-8464-6543)
- Cyril Ollivier (ORCID: https://orcid.org/0000-0003-2416-4467)
- Pierre Dedieu (ORCID: https://orcid.org/0009-0002-4429-5819)
- Fabian Bruel
Institutions
- Conservatoire National des Arts et Métiers (FR)
- Centre National de la Recherche Scientifique (FR)
- Chimie ParisTech - PSL (FR)
- Université Sorbonne Nouvelle (FR)
- Collège de France (FR)
- Université Paris Sciences et Lettres (FR)
- Institut de Mathématiques de Jussieu-Paris Rive Gauche (FR)
- Sorbonne Université (FR)
- Institut de Recherche de Chimie Paris (FR)
- Institut Parisien de Chimie Moléculaire (FR)
Publication Details
- Journal
- Green Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5gc02405f
- Primary Topic
- Chemical Reactions and Isotopes
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Centre National de la Recherche Scientifique