Two-step synthesis of amino-methyl- <i>N</i> -phenylcarbamate from toluidine: new preparative method and mechanism
A new two-step route, i.e. , p -toluidine first reacted with dimethyl carbonate to form metholylcarbamate (MTCM), and then MTCM further converted to amino-methyl- N -phenylcarbamate (TMC), was realized in this work.
Authors
- Yanji Wang (ORCID: https://orcid.org/0000-0003-2862-0992)
- Xiaoshu Ding (ORCID: https://orcid.org/0000-0002-7902-937X)
- Xiangyu Wen
- Xinqiang Zhao
- Dongsheng Zhang (ORCID: https://orcid.org/0000-0002-1331-379X)
- Ming Li (ORCID: https://orcid.org/0000-0003-2197-2178)
- Lu Yao (ORCID: https://orcid.org/0000-0003-2743-758X)
- Peng Zhai (ORCID: https://orcid.org/0000-0001-6196-2658)
- Qiusheng Yang
Institutions
- Hebei University of Technology (CN)
- Green Chemistry (PL)
Publication Details
- Journal
- Reaction Chemistry & Engineering
- Published
- 2025-09-10
- DOI
- https://doi.org/10.1039/d5re00246j
- Primary Topic
- Chemical Synthesis and Analysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00