Visible-Light-Induced Cascade Cyclization of Isocyanobiaryls with Hydrosilanes for the Synthesis of 6-Silylated Phenanthridines
A visible-light-induced cascade cyclization of isocyanobiaryls with hydrosilanes has been developed for the synthesis of 6-silylated phenanthridines. Readily available hydrosilanes were employed as silyl radical precursors under room-temperature conditions. The merits of the transformation include operational simplicity, mild conditions, high atom economy, and good functional group compatibility.
Authors
- Yanqi Li (ORCID: https://orcid.org/0000-0002-1437-9301)
- Heyun Sheng (ORCID: https://orcid.org/0009-0005-4614-9745)
- Yanping Li (ORCID: https://orcid.org/0009-0009-6677-1768)
- Yongqi Yu (ORCID: https://orcid.org/0000-0001-6086-7851)
- Weiguang Kong (ORCID: https://orcid.org/0000-0002-0690-724X)
- Ting Li (ORCID: https://orcid.org/0000-0002-2186-6992)
- Ming Chen (ORCID: https://orcid.org/0000-0003-1533-3409)
- Wenguang Li (ORCID: https://orcid.org/0009-0003-4969-4621)
- Mengdan You
Institutions
- Nanyang Normal University (CN)
- Pharmaceutical Biotechnology (Czechia) (CZ)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2025-09-09
- DOI
- https://doi.org/10.1021/acs.joc.5c01891
- Citations
- 2
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 1.87