UVA/B-Selective Skin-Inspired Nociceptors Based on Green Double Perovskite QDs-Sensitized 2D Semiconductor toward Reliable Human Somatosensory System Simulation

Achieving UVA/B-selective, skin-inspired nociceptors with perception and blockade functions at the single-unit device level remains challenging. This is because the device necessitates distinct components for every performance metric, thereby leading to complex preparation processes and restricted performance, as well as the absence of deep UV (UVB and below)-selective semiconductors. Here, to address this, we develop a structure-simplification skin-inspired nociceptor using a reverse type-II Cu<sub>2</sub>AgSbI<sub>6</sub>/MoS<sub>2</sub> heterostructure. It integrates excellent UVA/B sensitization gain in Cu<sub>2</sub>AgSbI<sub>6</sub>, surpassing traditional Cu<sub>2</sub>AgM<sup>III</sup>I<sub>6</sub>-based QDs in delocalization and bond energy, and exhibits efficient multifield modulated charge self-trapping transport. Consequently, the hybrid phototransistor shows significant increases in detectivity (30/14 times) and photoresponsivity (6.4/7.2 times) under 365/280 nm UV illumination. Moreover, it can reliably mimic computational capabilities with unusual adaptivity for skin-inspired nociceptor functions, achieving an unusual neural blocking degree of approximately 52%. This work presents a new approach for designing complex bionic functions in 2D materials for advanced neuromorphic photoelectronics.

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Publication Details

Journal
The Journal of Physical Chemistry Letters
Published
2025-09-09
DOI
https://doi.org/10.1021/acs.jpclett.5c02051
Citations
2
Primary Topic
Perovskite Materials and Applications
Type
article
Field-Weighted Citation Impact
1.46
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article

UVA/B-Selective Skin-Inspired Nociceptors Based on Green Double Perovskite QDs-Sensitized 2D Semiconductor toward Reliable Human Somatosensory System Simulation

Kailiang Zhang, Kai Hu, Jianzhou Ren, Z. Q. Liu et al.
2 citations
The Journal of Physical Chemistry Letters
Perovskite Materials and Applications
1.46
article

UVA/B-Selective Skin-Inspired Nociceptors Based on Green Double Perovskite QDs-Sensitized 2D Semiconductor toward Reliable Human Somatosensory System Simulation

Kailiang Zhang, Kai Hu, Jianzhou Ren, Z. Q. Liu, Yuchan Wang, Hongling Guo, Wenxia Zhang, Chenhao Xu, Lei Zheng, Ting Chen
article en
2 citations

Abstract

Achieving UVA/B-selective, skin-inspired nociceptors with perception and blockade functions at the single-unit device level remains challenging. This is because the device necessitates distinct components for every performance metric, thereby leading to complex preparation processes and restricted performance, as well as the absence of deep UV (UVB and below)-selective semiconductors. Here, to address this, we develop a structure-simplification skin-inspired nociceptor using a reverse type-II Cu<sub>2</sub>AgSbI<sub>6</sub>/MoS<sub>2</sub> heterostructure. It integrates excellent UVA/B sensitization gain in Cu<sub>2</sub>AgSbI<sub>6</sub>, surpassing traditional Cu<sub>2</sub>AgM<sup>III</sup>I<sub>6</sub>-based QDs in delocalization and bond energy, and exhibits efficient multifield modulated charge self-trapping transport. Consequently, the hybrid phototransistor shows significant increases in detectivity (30/14 times) and photoresponsivity (6.4/7.2 times) under 365/280 nm UV illumination. Moreover, it can reliably mimic computational capabilities with unusual adaptivity for skin-inspired nociceptor functions, achieving an unusual neural blocking degree of approximately 52%. This work presents a new approach for designing complex bionic functions in 2D materials for advanced neuromorphic photoelectronics.

The Journal of Physical Chemistry LettersVol. 16(37)
Chongqing University of Posts and Telecommunications (CN), Tianjin University of Technology (CN), Jilin University (CN), Chemical Synthesis Lab (SG), State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
Openalex Percentile: Top 15%
Perovskite Materials and Applications
1.46
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