Desulfurization of model oil using date kernel-derived activated carbon modified with pyridinium-based ionic liquids

In this study, activated carbon was produced from date kernels (DN-AC) as a low-cost precursor, and its properties, including surface area, were investigated. The activated carbon was then impregnated with the ionic liquid 1-methyl-4-ethylpyridinium iodide ([MEPI]) for use in the desulfurization of a petroleum derivative containing dibenzothiophene (DBT) dissolved in an n-hexane solvent. The results showed that the prepared activated carbon exhibited a high sulfur removal capacity under various experimental conditions, which were optimized to evaluate its reusability. The loaded carbon was characterized using many techniques, including surface area measurement, energy-dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), and thermal analysis, before being applied in the desulfurization process. KEY WORDS: Activated carbon, Ionic liquids, Desulfurization, BET, Surface area Bull. Chem. Soc. Ethiop. 2025, 39(10), 2065-2077. DOI: https://dx.doi.org/10.4314/bcse.v39i10.13

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Publication Details

Journal
Bulletin of the Chemical Society of Ethiopia
Published
2025-09-01
DOI
https://doi.org/10.4314/bcse.v39i10.13
Primary Topic
Catalysis and Hydrodesulfurization Studies
Type
article
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article

Desulfurization of model oil using date kernel-derived activated carbon modified with pyridinium-based ionic liquids

Hussein Habeeb Mustafa, Qaidar Salim Jarjees, Aws Nazar Abdlaziz
Bulletin of the Chemical Society of Ethiopia
Catalysis and Hydrodesulfurization Studies
article

Desulfurization of model oil using date kernel-derived activated carbon modified with pyridinium-based ionic liquids

Hussein Habeeb Mustafa, Qaidar Salim Jarjees, Aws Nazar Abdlaziz
article en

Abstract

In this study, activated carbon was produced from date kernels (DN-AC) as a low-cost precursor, and its properties, including surface area, were investigated. The activated carbon was then impregnated with the ionic liquid 1-methyl-4-ethylpyridinium iodide ([MEPI]) for use in the desulfurization of a petroleum derivative containing dibenzothiophene (DBT) dissolved in an n-hexane solvent. The results showed that the prepared activated carbon exhibited a high sulfur removal capacity under various experimental conditions, which were optimized to evaluate its reusability. The loaded carbon was characterized using many techniques, including surface area measurement, energy-dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), and thermal analysis, before being applied in the desulfurization process. KEY WORDS: Activated carbon, Ionic liquids, Desulfurization, BET, Surface area Bull. Chem. Soc. Ethiop. 2025, 39(10), 2065-2077. DOI: https://dx.doi.org/10.4314/bcse.v39i10.13

Bulletin of the Chemical Society of EthiopiaVol. 39(10)
University of Mosul
Openalex Percentile: Top 76%
Catalysis and Hydrodesulfurization Studies
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