General Strategy to Synthesize Star-Shaped Nanographenes with Controllable Symmetries

Nanographenes with diverse topological structures have shown enormous potential in fields such as photonics, optoelectronics, and spintronics. This work employs a "from-core-to-branch" strategy to controllably synthesize star-shaped nanographenes with various symmmetries. The obtained star-shaped nanographenes exhibit symmetry-dependent HOMO-LUMO gaps and photoluminescence quantum yields, revealing the importance of precisely controlling the molecular topologies. This work opens a new avenue to expand the chemical space of star-shaped nanographenes with tunable properties.

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Journal
Organic Letters
Published
2025-09-05
DOI
https://doi.org/10.1021/acs.orglett.5c03067
Primary Topic
Synthesis and Properties of Aromatic Compounds
Type
article
Field-Weighted Citation Impact
0.00

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article

General Strategy to Synthesize Star-Shaped Nanographenes with Controllable Symmetries

Yingcui Cui, Yanbin Shao, Kui Wang, Debin Xia et al.
Organic Letters
Synthesis and Properties of Aromatic Compounds
article

General Strategy to Synthesize Star-Shaped Nanographenes with Controllable Symmetries

Yingcui Cui, Yanbin Shao, Kui Wang, Debin Xia, Changding Guo, Zhiqiang Luo, Yuan Zhang, Xingyu Chen, Xiaoye Wang, Jing Guan, Xinna Ma
article en

Abstract

Nanographenes with diverse topological structures have shown enormous potential in fields such as photonics, optoelectronics, and spintronics. This work employs a "from-core-to-branch" strategy to controllably synthesize star-shaped nanographenes with various symmmetries. The obtained star-shaped nanographenes exhibit symmetry-dependent HOMO-LUMO gaps and photoluminescence quantum yields, revealing the importance of precisely controlling the molecular topologies. This work opens a new avenue to expand the chemical space of star-shaped nanographenes with tunable properties.

Organic LettersVol. 27(37)
Harbin Medical University (CN), Harbin Institute of Technology (CN), Nankai University (CN), Institute of Organic Chemistry (PL), Institute of Organic Chemistry (HU), Sungkyunkwan University (KR)
Harbin Medical University, National Natural Science Foundation of China, Natural Science Foundation of Heilongjiang Province, Key Laboratory of Functional Inorganic Materials Chemistry Ministry of Education
Openalex Percentile: Top 82%
Synthesis and Properties of Aromatic Compounds
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General Strategy to Synthesize Star-Shaped Nanographenes with Controllable Symmetries — Yingcui Cui, Yanbin Shao, et al. · Organic Letters (2025) | TGRS Research Map | TGRS