Synthesis of Pectin Hydrogels from Grapefruit Peel for the Adsorption of Heavy Metals from Water

The increasing presence of heavy metals in aquatic environments, driven by the production of industrial waste and consumer products, poses serious environmental and health risks due to their toxicity and persistence. Copper (Cu(II)) and nickel (Ni(II)) are particularly harmful, with high concentrations linked to neurological, dermatological and carcinogenic effects. This proof-of-concept study explores the synthesis of sustainable hydrogels derived from grapefruit peel (biosorbents) for the adsorption of Cu(II) and Ni(II) from aqueous solutions. Pectin was extracted from the peels and was used to synthesize pectin-based hydrogels (PH) and pectin hydrogel metal–organic frameworks (PHM composites). The hydrogels were characterized using FT-IR, SEM, diameter size and water absorption capacity. Lyophilized hydrogels were significantly smaller than their wet counterparts, and adsorption performance was analyzed using FAAS. PHs demonstrated high Cu(II) removal efficiency, achieving 95.11% adsorption and 97.75 mg/g capacity at pH 5. PHM composites showed comparable Cu(II) adsorption with a maximum capacity of 67.53 mg/g. Notably, PHs also exhibited rapid Ni(II) adsorption, reaching 92.62% efficiency and 28.189 mg/g capacity within one minute. These findings highlight the potential of pectin-based hydrogels as an effective, low-cost and environmentally friendly method for heavy metal remediation in water.