Versatility of Surfactant‐Mediated NiTe <sub>2</sub> Nanoparticles: Unlocking Potential for Hydrogen Evolution Reaction, Supercapacitor, and Sustainable Green Catalysis
Designing multifunctional nanomaterials is economically and practically advantageous. Herein, this work reports a surfactant-mediated synthesis of NiTe<sub>2</sub> nanoparticles (NPs) and their applications in electrocatalysis, energy storage, and sustainable green catalysis. The NiTe<sub>2</sub> NPs exhibit excellent hydrogen evolution reaction (HER) activity, with a low overpotential of 309 mV versus RHE at 10 mA cm<sup>-2</sup> and a Tafel slope of 50 mV dec<sup>-1</sup>, indicating fast kinetics. As supercapacitor (SC) electrodes, they deliver a high specific capacitance of 620 F g<sup>-1</sup> at 1 A g<sup>-1</sup>, retaining 62% at 10 A g<sup>-1</sup> and 78.3% after 5000 cycles. An asymmetric coin cell (ASC) achieves 75.3 F g<sup>-1</sup> specific capacitance, 30.6 Wh kg<sup>-1</sup> energy density, and 914.6 W kg<sup>-1</sup> power density, with 76.4% capacitance retention and 93.7% efficiency after 5000 cycles. Additionally, NiTe<sub>2</sub> NPs enable the sustainable synthesis of quinolines and 2-aminoquinolines, achieving up to 97% yield under mild conditions with only 0.00563 mmol (in 10 mg) catalyst loading. These results underscore the versatility of NiTe<sub>2</sub> NPs as a cost-effective, high-performance material for clean energy and green chemistry applications.
Authors
- C. Manjunatha
- Partha Pratim Roy (ORCID: https://orcid.org/0000-0002-5735-5254)
- M. Iqbal Choudhary (ORCID: https://orcid.org/0000-0001-5356-3585)
- Ashish Ranjan Dwivedi (ORCID: https://orcid.org/0000-0002-0918-6062)
- Neha Mathur (ORCID: https://orcid.org/0000-0002-1234-6629)
- Pankaj Gupta (ORCID: https://orcid.org/0000-0001-7689-4352)
- Jatin Nama (ORCID: https://orcid.org/0000-0002-4809-5585)
- Sayed A. Shama
- Hemant Joshi (ORCID: https://orcid.org/0000-0002-7616-0241)
- Shwetha KP
Institutions
- Indian Institute of Technology Gandhinagar (IN)
- Nanomaterials Research (United States) (US)
- Central University of Rajasthan (IN)
Publication Details
- Journal
- Small
- Published
- 2025-09-05
- DOI
- https://doi.org/10.1002/smll.202507377
- Citations
- 1
- Primary Topic
- Electrocatalysts for Energy Conversion
- Type
- article
- Field-Weighted Citation Impact
- 0.36
Funders
- Science and Engineering Research Board