FeNiS/PANI Hybrid Composite for Enhanced Electrochemical Energy Storage Performance

This study focuses on developing FeNiS/PANI composites for supercapacitor applications, leveraging the individual benefits of iron–nickel sulfide (FeNiS) and polyaniline (PANI). FeNiS offers high electrical conductivity and energy density, while PANI contributes enhanced flexibility and pseudocapacitive behavior. The goal is to create a composite with superior electrochemical performance. Synthesis involved chemical oxidative polymerization for PANI and an in situ method for FeNiS, followed by integration. Characterization techniques like XRD, SEM, and EDS confirmed the successful formation and homogeneous elemental dispersion of the composite, showing that PANI formed an interconnected network that improved charge transport. Electrochemical analysis demonstrated significant improvements. Cyclic voltammetry (CV) and galvanostatic charge–discharge (GCD) tests revealed that the FeNiS/PANI composite exhibited a doubled discharge time (159 s vs. 72 s for FeNiS) and a higher specific capacitance (113.5 F/g vs. 51.42 F/g). These results highlight the promise of FeNiS/PANI as an advanced material for efficient and sustainable energy storage.