Kinetics and Evolution Modeling of Hydrogen-Induced Cracking in Low-Carbon Steel.

The kinetics and evolution of hydrogen-induced cracking (HIC) were modeled using a theoretical model developed by Gonzalez to calculate the individual crack growth rate and a computational algorithm based on a Poisson distribution to generate the initial spatial distribution of HIC nuclei. Additionally, the Monte Carlo method was used to model the interconnection of individual HIC cracks. The results of the computational model were compared versus experimental results of HIC induced by cathodic charging experiments in low-carbon steel plates. The model was capable of accurately emulating the kinetics of HIC, considering the first stage of nucleation and growth of randomly dispersed individual HIC cracks, followed by a second stage where the individual cracks interconnect with each other to form large cracks that subsequently grow. The study was complemented with the fractographic examination of the HIC cracks to verify if the fracture mechanism is consistent with the crack morphology and propagation mode in the proposed model. The results indicate that HIC propagation occurs by cleavage and quasi-cleavage mechanisms, with crack interconnection by ductile shear tearing, where the driving force for HIC is the accumulated hydrogen pressure within the internal HIC cracks, explaining why the crack growth rates are nearly constant in each stage of HIC growth.