Phosphorylation of nitrogen-doped carbon stabilizes Rh clusters for selective hydroformylation of alkenes to linear aldehydes
A phosphorylation strategy was used to fabricate a hollow phosphorus- and nitrogen-doped carbon material encapsulating Rh nanoclusters. Phosphorus doping creates an electronic effect that enhances alkene hydroformylation selectivity, yielding a linear-to-branched aldehyde ratio above 7.
Authors
- Suxia Liang (ORCID: https://orcid.org/0000-0003-1919-6747)
- Dongrun Wang
- Jiantai Ma (ORCID: https://orcid.org/0000-0003-3133-7696)
- Zhengping Dong (ORCID: https://orcid.org/0000-0003-0775-1133)
- Guiqin Yu
- Chuang Liu
Institutions
- Lanzhou University (CN)
Publication Details
- Journal
- Catalysis Science & Technology
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cy00873e
- Citations
- 1
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.94