Dynamic Nanocrystal Superlattices Mediated by Hofmeister Effect Ligands

Surface functionalization of colloidal nanocrystals (NCs) with ion-specific polymeric ligands enables programmable modulation of ligand hydrophilicity-hydrophobicity <i>via</i> the Hofmeister effect. This control drives NC rearrangement and reorientation, triggering a directed topological transformation from glassy aggregates into thermodynamically favorable, close-packed nanocrystal superlattices with high crystallinity.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc03997e
Primary Topic
Spectroscopy and Quantum Chemical Studies
Type
article
Field-Weighted Citation Impact
0.00
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article

Dynamic Nanocrystal Superlattices Mediated by Hofmeister Effect Ligands

Xuejie Liu, Yanqiu Du, Y. D. Yao, Nan Yan et al.
Chemical Communications
Spectroscopy and Quantum Chemical Studies
article

Dynamic Nanocrystal Superlattices Mediated by Hofmeister Effect Ligands

Xuejie Liu, Yanqiu Du, Y. D. Yao, Nan Yan, Yuhui Wang, Haidong Li, Pingfan Wang
article en

Abstract

Surface functionalization of colloidal nanocrystals (NCs) with ion-specific polymeric ligands enables programmable modulation of ligand hydrophilicity-hydrophobicity <i>via</i> the Hofmeister effect. This control drives NC rearrangement and reorientation, triggering a directed topological transformation from glassy aggregates into thermodynamically favorable, close-packed nanocrystal superlattices with high crystallinity.

Chemical CommunicationsVol. 61(82)
Changchun Normal University (CN), Jiaxing University (CN)
Openalex Percentile: Top 82%
Spectroscopy and Quantum Chemical Studies
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Dynamic Nanocrystal Superlattices Mediated by Hofmeister Effect Ligands — Xuejie Liu, Yanqiu Du, et al. · Chemical Communications (2025) | TGRS Research Map | TGRS