Systematic Study of CDOM in the Volga River Basin Using EEM-PARAFAC

This manuscript continues a series of papers devoted to the study of bio-optical characteristics of the Volga River waters in the context of development of regional bio-optical models. A particularly weak point in this effort is the limited knowledge of dissolved organic matter (DOM): its component composition, spectral absorption characteristics, and the lack of satellite-based assessment algorithms. Using excitation–emission matrix fluorescence spectroscopy, we examined the fluorescent fraction of DOM of surface water layer of the Volga River and its tributaries in the area from the Gorky Reservoir to the Volgograd Reservoir, a stretch spanning over 1500 km, in the period from May to September 2022–2024. Four fluorescent components were validated in parallel factor analysis. The ratio of fluorescent components was mostly stable, while their fluorescence intensities varied a lot. For example, the fluorescence intensity of the DOM of the Gorky Reservoir and the Kama River differed by more than 2.5-fold. The highest FDOM fluorescence was found in the Gorky Reservoir. Downstream, it decreased due to the inflow of the Oka and Kama rivers. The influence of small rivers such as Kerzhenets, Sundovik, Sura, and Vetluga was insignificant. It is demonstrated that neither conventional remote sensing techniques (LiDAR) plus in situ measurements of DOM with a probe nor DOM absorption at 440 nm allows probing all the fluorescent components, so their efficiency is determined by the correlation of fluorophore group content.