Improving CO2 Capture Efficiency Through Novel CLOU-Based Fuel Reactor Configuration in Chemical Looping Combustion

Climate change and global decarbonization targets drive the search for more efficient and cost-effective combustion technologies. Chemical looping combustion (CLC) using solid oxygen carriers with chemical looping with oxygen uncoupling (CLOU) functionality has attracted growing interest due to its inherent potential for CO2 capture without requiring additional separation processes. This study introduces a conceptual proof-of-concept design of a novel fuel reactor design for a dual-fluidized bed CLC system operating with solid fuels. The new configuration incorporates a perforated conveyor for circulating CLOU-type oxygen carriers, thereby avoiding direct contact between the carriers and the fuel–ash mixture. This approach prevents the slip of unburned fuel and ash into the air reactor, minimizes the loss of oxygen carriers, and improves combustion efficiency. The proposed reactor concept enables the generation of flue gas with a high CO2 concentration, which facilitates its subsequent capture and reduces the energy penalty associated with traditional CCS techniques. The improved phase separation and better control of oxygen carrier residence time contribute to enhanced system performance and reduced operating costs. Preliminary process simulations conducted in the CeSFaMB environment, using boundary and initial conditions from a CLC test rig, were included to illustrate the potential of the design. Experimental validation is outside the scope of this study and will be presented in future work once the dedicated test facility is operational. This contribution should therefore be regarded as a conceptual proof-of-concept study, and experimental validation together with techno-economic benchmarking will be reported in follow-up publications once the dedicated test facility is operational.