Visible-light-induced stereoselective trifluoromethylselenolation of arylalkenyl iodides with [Me<sub>4</sub>N][SeCF<sub>3</sub>]

The photocatalytic stereoselective trifluoromethylselenolation of <i>E</i>-arylalkenyl iodides with [Me<sub>4</sub>N][SeCF<sub>3</sub>] is described under different conditions. These reactions enabled the first controllable synthesis of arylalkenyl trifluoromethyl selenoethers in good yields and with high <i>E</i>- or <i>Z</i>-selectivity.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc03765d
Primary Topic
Fluorine in Organic Chemistry
Type
article
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article

Visible-light-induced stereoselective trifluoromethylselenolation of arylalkenyl iodides with [Me4N][SeCF3]

Hai-Lun Wan, Fuyan Xiao, Cheng‐Pan Zhang, Yanhao Wang
Chemical Communications
Fluorine in Organic Chemistry
article

Visible-light-induced stereoselective trifluoromethylselenolation of arylalkenyl iodides with [Me4N][SeCF3]

Hai-Lun Wan, Fuyan Xiao, Cheng‐Pan Zhang, Yanhao Wang
article en

Abstract

The photocatalytic stereoselective trifluoromethylselenolation of <i>E</i>-arylalkenyl iodides with [Me<sub>4</sub>N][SeCF<sub>3</sub>] is described under different conditions. These reactions enabled the first controllable synthesis of arylalkenyl trifluoromethyl selenoethers in good yields and with high <i>E</i>- or <i>Z</i>-selectivity.

Chemical CommunicationsVol. 61(80)
Wuhan University of Technology (CN), Wuhan University (CN)
Openalex Percentile: Top 83%
Fluorine in Organic Chemistry
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