Examination the Corrosion Inhibition of Synthesized Azo-Schiff Bases Compounds from (P-Fluorophenyl)-1,3,4-Thiadiazoles for Carbon Steel Alloy in Acidic Medium

New azo-Schiff base compounds were prepared by different processes using (p-fluorophenyl)-1,3,4-thiadiazoles, and their role as corrosion inhibitors for carbon steel alloy in acidic media such as 0.1 M HCl at 298 K was investigated. Spectroscopic methods such as FT-IR and NMR were used to characterise the compounds, and potentiodynamic polarization curves were employed to evaluate their corrosion inhibition. p-Aminoacetophenone was react withed 2-(5-(4-fluorophenyl)-1,3,4-thiadiazol-2-yl) acetohydrazide (A1) to prepare N ′-(1-(4-aminophenyl) ethylidene)-2-(5-(4-fluorophenyl)-1,3,4-thiadiazol-2-yl) acetohydrazide (A2). Azo-Schiff bases (A3-A6) were synthesised by combining the prepared diazonium salts with different phenols. These compounds’ structures were changed to improve their ability to prevent corrosion in a range of industrial settings, especially for metals exposed to acidic environments. The inhibitory efficiency percentage was between 76% and 90%. At 90%, the synthetic medication (A6) obtained the highest value. The formed protective adsorption coating on the steel surface was the reason for the improved inhibitor activity. These findings imply that the artificial Azo-Schiff bases show promising application as corrosion inhibitors for carbon steel in acidic settings. Applications in sectors where corrosion resistance is crucial may benefit from this knowledge.

Authors

Institutions

Publication Details

Journal
Al-Khwarizmi Engineering Journal
Published
2025-09-01
DOI
https://doi.org/10.22153/kej.2025.09.004
Primary Topic
Material Properties and Applications
Type
article
Field-Weighted Citation Impact
0.00
Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Examination the Corrosion Inhibition of Synthesized Azo-Schiff Bases Compounds from (P-Fluorophenyl)-1,3,4-Thiadiazoles for Carbon Steel Alloy in Acidic Medium

Ahmed Naser, Khadija Najah Zaidane
Al-Khwarizmi Engineering Journal
Material Properties and Applications
article

Examination the Corrosion Inhibition of Synthesized Azo-Schiff Bases Compounds from (P-Fluorophenyl)-1,3,4-Thiadiazoles for Carbon Steel Alloy in Acidic Medium

Ahmed Naser, Khadija Najah Zaidane
article en

Abstract

New azo-Schiff base compounds were prepared by different processes using (p-fluorophenyl)-1,3,4-thiadiazoles, and their role as corrosion inhibitors for carbon steel alloy in acidic media such as 0.1 M HCl at 298 K was investigated. Spectroscopic methods such as FT-IR and NMR were used to characterise the compounds, and potentiodynamic polarization curves were employed to evaluate their corrosion inhibition. p-Aminoacetophenone was react withed 2-(5-(4-fluorophenyl)-1,3,4-thiadiazol-2-yl) acetohydrazide (A1) to prepare N ′-(1-(4-aminophenyl) ethylidene)-2-(5-(4-fluorophenyl)-1,3,4-thiadiazol-2-yl) acetohydrazide (A2). Azo-Schiff bases (A3-A6) were synthesised by combining the prepared diazonium salts with different phenols. These compounds’ structures were changed to improve their ability to prevent corrosion in a range of industrial settings, especially for metals exposed to acidic environments. The inhibitory efficiency percentage was between 76% and 90%. At 90%, the synthetic medication (A6) obtained the highest value. The formed protective adsorption coating on the steel surface was the reason for the improved inhibitor activity. These findings imply that the artificial Azo-Schiff bases show promising application as corrosion inhibitors for carbon steel in acidic settings. Applications in sectors where corrosion resistance is crucial may benefit from this knowledge.

Al-Khwarizmi Engineering JournalVol. 21(3)
University of Baghdad (IQ), University of Technology - Iraq (IQ)
Openalex Percentile: Top 64%
Material Properties and Applications
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.