Palladium nanoparticles immobilized in SnFe2O4/SiO2/PM as efficient heterogeneous catalysts for the suzuki cross-coupling reaction
This study focuses on the synthesis of a novel magnetic interphase palladium catalyst immobilized on pyromellitic dianhydride (PM)-coated magnetic SnFe<sub>2</sub>O<sub>4</sub> nanoparticles. Such surface functionalization of magnetic particles represents a promising strategy to bridge the gap between heterogeneous and homogeneous catalysis methods. The structure, morphology, and physicochemical properties of these particles were thoroughly examined using various analytical techniques, including FT-IR, SEM, XRD, VSM, ICP, and EDS. The resulting SnFe<sub>2</sub>O<sub>4</sub>/SiO<sub>2</sub>/PM-Pd nanocatalyst exhibited excellent catalytic performance as a recyclable catalyst in Suzuki-Miyaura cross-coupling reactions at room temperature. Additionally, the catalyst demonstrated high reusability, showing minimal palladium leaching and no significant loss in activity across multiple cycles.
Authors
- Swati Mishra (ORCID: https://orcid.org/0000-0001-8108-7942)
- Jayanti Makasana (ORCID: https://orcid.org/0000-0001-5959-3419)
- Suhas Ballal (ORCID: https://orcid.org/0000-0002-6041-8332)
- Magda H. Abdellattif (ORCID: https://orcid.org/0000-0002-8562-4749)
- Anjan Kumar (ORCID: https://orcid.org/0000-0002-0451-6042)
- T. Krithiga
- Abhayveer Singh (ORCID: https://orcid.org/0000-0001-8536-4281)
- Chou-Yi Hsu (ORCID: https://orcid.org/0009-0000-5290-7198)
- Pushpa Negi Bhakuni
- Munther Kadheem
Institutions
- Jain University (IN)
- Taif University (SA)
- Siksha O Anusandhan University (IN)
- Iraqi University (IQ)
- Marwadi University (IN)
- Institute of Medical Sciences and Sum Hospital (IN)
- Sathyabama Institute of Science and Technology (IN)
- Arizona State University (US)
- Graphic Era University (IN)
- Chitkara University (IN)
- GLA University (IN)
Publication Details
- Journal
- Scientific Reports
- Published
- 2025-08-31
- DOI
- https://doi.org/10.1038/s41598-025-16233-9
- Citations
- 1
- Primary Topic
- Catalytic Cross-Coupling Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.94
Funders
- Taif University