Revisiting Pisarenko’s formula: Effective mass estimation, thermopower–conductivity relation, and maximum power factor prediction

The thermopower α (also known as the Seebeck coefficient) is one of the most fundamental material characteristics for understanding charge carrier transport in thermoelectric materials. Here, we revisit the Pisarenko formula for the thermopower, which was traditionally considered valid only for non-degenerate semiconductors. We demonstrate that regardless of the dominating scattering mechanism, the Pisarenko formula describes accurately enough the relationship between thermopower α and charge carrier concentration n beyond the non-degenerate limit. Moreover, the Pisarenko formula provides a simple thermopower-conductivity relation, α = ± k B e ( b − ln σ ) , where b is a constant determined by the scattering mechanism and weighted mobility μ w , and σ is the electrical conductivity. This relation is valid for materials with α > 90 µ V K − 1 when acoustic phonon scattering is predominant. This offers an alternative way to analyze electron transport when Hall measurements are difficult or inaccessible. Additionally, we show how the Pisarenko formula can be used to estimate the maximum power factor of a thermoelectric material from the weighted mobility of a single, not necessarily optimized, sample at any given temperature. • Pisarenko formula demonstrated to be applicable beyond the non-degenerate semiconductor limit. • Thermopower value of 150 µV K -1 is identified as threshold for accurate effective mass estimation. • α -ln σ plot proposed as a tool for carrier transport analysis. • Analytical prediction of maximum power factor from weighted mobility is demonstrated.