Defect engineering in Sb<sub>2</sub>Se<sub>3</sub> via post-growth thermal treatments: a photoluminescence study

Sb2Se3 is an emerging inorganic quasi-one-dimensional (Q1D) semiconductor absorber material for sustainable thin film photovoltaics. The efficiency of Sb2Se3 solar cells is mainly limited by the strong recombination of light-induced charge carriers resulting in low open circuit voltage of the devices. A route to suppress the formation of harmful deep defects in Sb2Se3 limiting the carrier lifetime, mobility and concentration via post-growth thermal treatment is presented in this study. The defects in the as-grown and post-growth heat-treated Sb2Se3 polycrystals are investigated by detailed photoluminescence spectroscopy.

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Published
2025-06-08
DOI
https://doi.org/10.1109/pvsc59419.2025.11132953
Primary Topic
Chalcogenide Semiconductor Thin Films
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article
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Defect engineering in Sb2Se3 via post-growth thermal treatments: a photoluminescence study

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Defect engineering in Sb2Se3 via post-growth thermal treatments: a photoluminescence study

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article en

Abstract

Sb2Se3 is an emerging inorganic quasi-one-dimensional (Q1D) semiconductor absorber material for sustainable thin film photovoltaics. The efficiency of Sb2Se3 solar cells is mainly limited by the strong recombination of light-induced charge carriers resulting in low open circuit voltage of the devices. A route to suppress the formation of harmful deep defects in Sb2Se3 limiting the carrier lifetime, mobility and concentration via post-growth thermal treatment is presented in this study. The defects in the as-grown and post-growth heat-treated Sb2Se3 polycrystals are investigated by detailed photoluminescence spectroscopy.

Tallinn University of Technology (EE)
Openalex Percentile: Top 78%
Chalcogenide Semiconductor Thin Films
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