Effect of Cold Rolling on Microstructure Evolution and Mechanical Properties of Zn-3Cu-1Mg-0.3Nd Alloy

Biodegradable zinc alloys for orthopedic implants must balance mechanical strength and plasticity, yet current as-cast alloys struggle to meet this dual requirement. In this study, a Zn-3Cu-1Mg-0.3Nd alloy was designed, and the influence of room-temperature rolling at four reduction levels (50%, 60%, 70%, and 80%) on its microstructure and mechanical properties was systematically investigated. Results indicate that as the reduction increases, the CuZn5 phase elongated along the rolling direction, and the η-Zn+Mg2Zn11 eutectic structure was progressively fragmented. The average grain size of the η-Zn matrix decreased significantly from 18.9 μm (50% reduction) to 1.71 μm (80% reduction). A distinct bimodal heterogeneous microstructure (coarse/fine grains) was formed at 60% and 70% reductions, while a predominantly fine-grained structure (91.3% fine grains) was achieved at 80% reduction. Furthermore, cracks initiated in the NdZn11 phase due to stress concentration during rolling. As the rolling reduction increases, the alloy’s ultimate tensile strengths (UTS) initially rose and then declined (peaking at 417 ± 5 MPa at 60% reduction), while its elongation (EL) consistently improved. At 80% reduction, the alloy exhibited optimal mechanical properties, achieving a tensile strength of 406 ± 4 MPa and an EL of 16.4 ± 0.3%, both significantly higher than those of the as-cast alloy (126 MPa, 4.4%). The enhancement in strength is attributed to a multi-scale synergistic mechanism involving grain refinement and back stress strengthening induced by heterogeneous microstructures. The continuous improvement in plasticity results from grain refinement, texture weakening, and the activation of non-basal <c+a> slip systems. Notably, cracks within the NdZn11 phase were confined by its high-binding-strength interface, preventing detrimental propagation into the matrix. This study elucidates the strengthening and toughening mechanisms in zinc alloys through cold rolling and the addition of the Nd element, particularly in terms of microstructural control and crack passivation, offering theoretical guidance for the design of biodegradable zinc alloy materials.