Controllable syntheses of two structurally new {AsW<sub>9</sub>O<sub>33</sub>}-mediated silver alkynyl clusters
In this work, two structurally new silver alkynyl clusters, [(AsW<sub>9</sub>O<sub>33</sub>)<sub>2</sub>@Ag<sub>48</sub>(NO<sub>3</sub>)<sub>6</sub>(<sup><i>t</i></sup>BuCC)<sub>24</sub>(DMF)<sub>6</sub>]·3CH<sub>3</sub>CN (1) and [(AsW<sub>9</sub>O<sub>33</sub>)<sub>2</sub>@Ag<sub>56</sub>(NO<sub>3</sub>)<sub>4</sub>Cl<sub>2</sub>(<sup><i>t</i></sup>BuCC)<sub>32</sub>]<sub><i>n</i></sub> (2), were successfully synthesized using the trilacunary B-α-[AsW<sub>9</sub>O<sub>33</sub>]<sup>9-</sup> as an anionic template <i>via</i> a facile one-pot solvothermal approach. The molecular structures of clusters 1 and 2 can be controlled using different mixed reaction solvents. Compounds 1 and 2 also demonstrate efficient photothermal conversion properties and notable catalytic activities towards the detoxification of 4-nitrophenol.
Authors
- Yurui Li (ORCID: https://orcid.org/0000-0002-4409-5086)
- Hongjin Lv (ORCID: https://orcid.org/0000-0002-9212-7572)
- Guo‐Yu Yang (ORCID: https://orcid.org/0000-0002-0911-2805)
- Tian‐Fu Liu (ORCID: https://orcid.org/0000-0001-9096-6981)
- Yeqin Feng
- Mengyun Zhao
- Qingqing Liu (ORCID: https://orcid.org/0009-0000-9751-518X)
Institutions
- Beijing Institute of Technology (CN)
Publication Details
- Journal
- Nanoscale
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5nr03313f
- Primary Topic
- Nanocluster Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00