A stable sulfate-pillared metal triazolate framework with a gating effect for highly efficient dehydration of bioethanol
Separation of ethanol-water azeotrope is extremely challenging. Here, we design and synthesize a new sulfate-pillared metal triazolate framework, which shows sieving-like separation of water/ethanol. A dynamic breakthrough verified the ultrahigh selectivity (145), and it could produce a record-breaking ethanol productivity (3.08 g g<sup>-1</sup>) with fuel-grade purity in a single adsorption process.
Authors
- Hao‐Long Zhou (ORCID: https://orcid.org/0000-0002-5007-6535)
- Wen-Jiang Tian
- Dong‐Dong Zhou (ORCID: https://orcid.org/0000-0003-1105-8702)
- Xiao‐Ming Chen (ORCID: https://orcid.org/0000-0002-3353-7918)
- Xiao‐Feng Zhong (ORCID: https://orcid.org/0000-0002-5639-2483)
- Ming Xue (ORCID: https://orcid.org/0000-0002-5011-3842)
- Ding-Yi Hu
- Zi-Luo Fang
Institutions
- Sun Yat-sen University (CN)
- Shantou University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc04344a
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00