Enhanced Interfacial Wettability and Retardancy of Cellulose Acetate/Ammonium Polyphosphate/Polyvinylidene Fluoride Ternary Composites Fabricated by One-Step Electrospinning

The cutting-edge development of lithium-ion batteries (LIBs) focuses on improving the security and cycle performance. The separator film plays an important role in cell performance and long-term service life, which requires both flame retardancy and mechanical strength. In this work, a one-step electrospinning technique has been adopted to prepare a novel polyvinylidene fluoride/cellulose acetate/ammonium polyphosphate membrane acting as a separator in the LIBs. The electrospinning conditions have been first optimized mainly by varying the concentration of precursor solution. The electrospun membranes have been characterized using scanning electron microscopy and infrared spectroscopy. The porosity, electrolyte uptake capability, the electrolyte wettability, thermal stability, and tensile properties have also been measured.

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Publication Details

Journal
ACS Omega
Published
2025-08-29
DOI
https://doi.org/10.1021/acsomega.5c04122
Primary Topic
Advanced Sensor and Energy Harvesting Materials
Type
article
Field-Weighted Citation Impact
0.00

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article

Enhanced Interfacial Wettability and Retardancy of Cellulose Acetate/Ammonium Polyphosphate/Polyvinylidene Fluoride Ternary Composites Fabricated by One-Step Electrospinning

Jiali Qiu, Yuefeng Su, Weifu Sun, Hongyuan Wen et al.
1 links
ACS Omega
Advanced Sensor and Energy Harvesting Materials
article

Enhanced Interfacial Wettability and Retardancy of Cellulose Acetate/Ammonium Polyphosphate/Polyvinylidene Fluoride Ternary Composites Fabricated by One-Step Electrospinning

Jiali Qiu, Yuefeng Su, Weifu Sun, Hongyuan Wen, Zhaoyin Ding, Jiayu Zhao
article en

Abstract

The cutting-edge development of lithium-ion batteries (LIBs) focuses on improving the security and cycle performance. The separator film plays an important role in cell performance and long-term service life, which requires both flame retardancy and mechanical strength. In this work, a one-step electrospinning technique has been adopted to prepare a novel polyvinylidene fluoride/cellulose acetate/ammonium polyphosphate membrane acting as a separator in the LIBs. The electrospinning conditions have been first optimized mainly by varying the concentration of precursor solution. The electrospun membranes have been characterized using scanning electron microscopy and infrared spectroscopy. The porosity, electrolyte uptake capability, the electrolyte wettability, thermal stability, and tensile properties have also been measured.

ACS OmegaVol. 10(35)
Beijing Institute of Technology (CN), City University of Hong Kong (HK), Nanjing University of Science and Technology (CN), Advanced Technology and Research Corporation (United States) (US), Environmental Protection Engineering (Greece) (GR), Jinan Institute of Quantum Technology (CN), Institute of Science and Technology, Chongqing University of Technology (CN)
National Natural Science Foundation of China, Natural Science Foundation of Chongqing, Taishan Scholar Project of Shandong Province, State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology Research Fund Program for Young Scholars, National Key Research and Development Program of China
Openalex Percentile: Top 79%
Advanced Sensor and Energy Harvesting Materials
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