Hybrid inorganic–organic polyhedral oligomeric silsesquioxane-based poly(1-haloacetylene)s: thermal, solid-state polymerization
Solid-state thermal polymerization of 1-haloacetylenes POSS gave stable, thermally resistant polymers. PolyPOSS-C2Cl, -C 2 Br , and -C 2 I show direct optical band gaps of 2.79, 2.74, and 2.38 eV, respectively.
Authors
- Mateusz Janeta (ORCID: https://orcid.org/0000-0003-2197-7913)
- Sławomir Szafert (ORCID: https://orcid.org/0000-0002-0570-8847)
- Marta Cieplucha
Institutions
- University of Wrocław (PL)
Publication Details
- Journal
- Materials Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qm00583c
- Primary Topic
- Silicone and Siloxane Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00