Clean and economic synthesis of <i>N</i> -sulfonyl isothioureas from isocyanides, sulfonamides and disulfides

An electrochemical three-component reaction of isocyanides, sulfonamides and disulfides is developed, in which a rare N-to-N [1,3]-H shift occurs. This is a highly efficient and cost-effective method for synthesizing N -sulfonyl isothioureas.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-01-01
DOI
https://doi.org/10.1039/d5qo00867k
Citations
2
Primary Topic
Sulfur-Based Synthesis Techniques
Type
article
Field-Weighted Citation Impact
1.87
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article

Clean and economic synthesis of N -sulfonyl isothioureas from isocyanides, sulfonamides and disulfides

Feng Jiang, Jingwei Lv, Changping Xun, Wenfeng Lv et al.
2 citations
Organic Chemistry Frontiers
Sulfur-Based Synthesis Techniques
1.87
article

Clean and economic synthesis of N -sulfonyl isothioureas from isocyanides, sulfonamides and disulfides

Feng Jiang, Jingwei Lv, Changping Xun, Wenfeng Lv, Zhibin Nong, Jiajun Zhao, Zhengnan Yin, Qingwen Gui, Kun Hu
article en
2 citations

Abstract

An electrochemical three-component reaction of isocyanides, sulfonamides and disulfides is developed, in which a rare N-to-N [1,3]-H shift occurs. This is a highly efficient and cost-effective method for synthesizing N -sulfonyl isothioureas.

Organic Chemistry FrontiersVol. 12(24)
Hunan Agricultural University (CN)
Openalex Percentile: Top 14%
Sulfur-Based Synthesis Techniques
1.87
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