Degradation of Polymers and Heavy Metals in Waste Drilling Fluid by Sulfur-Doped BiOBr0.5Cl0.5 Photocatalysts

Waste drilling fluids represent a complex gel-colloidal system containing structurally stable polymeric networks and heavy-metal ions that can cause tremendous damage to the ecosystem. The current disposal methods, like solidification/landfills, formation reinjection, and chemical treatment, commonly suffer from high secondary pollution risks, poor resource recovery, and incomplete detoxification. This paper developed a photocatalytic approach to complex gel system treatment by hydrothermally synthesizing a novel sulfur-doped, oxygen-vacancy-modified 3D flower-like xS-BiOBr_0.5Cl_0.5 structure which effectively narrowed the bandgap of BiOX and thus significantly enhanced its catalytic activity. The chemical composition, morphology, specific surface areas, and bandgaps of the materials were characterized. The photocatalytic performance and cyclic stability of the materials were measured, and 0.5S-BiOBr_0.5Cl_0.5 showed the best photocatalytic performance. The rhodamine B(RhB) degradation and polymer degradation efficiencies of 0.5S-BiOBr_0.5Cl_0.5 were up to 91% and 79%, respectively, while the Hg(II), Cr(VI), and Cr(III) reduction efficiencies of the material were up to 48.10%, 96.58%, and 96.41%, respectively. The photocatalytic mechanism of the xS-BiOBr_0.5Cl_0.5 materials was evaluated through an oxygen vacancy analysis, active species capture experiments, and density functional theory (DFT) computations. Overall, the xS-BiOBr_0.5Cl_0.5 materials can provide a low-cost and harmless treatment method for waste drilling fluids and promote the "green" development of oil and gas.