Enhancing Quantum Dot Photovoltaic Efficiency Through Defect Passivation and Triplet Energy Transfer with 9‐Anthracenecarboxylic Acid

A dual-functional electron transport layer (ETL) is reported for PbS colloidal quantum dot (CQD) photovoltaics by incorporating 9-anthracenecarboxylic acid (ACA) into a zinc oxide (ZnO) matrix. Despite its favorable electron transport characteristics and appropriate band alignment, intrinsic defects in ZnO, such as oxygen vacancies, remain a limiting factor in device performance. The carboxylate functional group of ACA effectively passivates these defects, thereby reducing trap-assisted recombination. Moreover, ACA, an acene-based π-conjugated molecule, efficiently generates triplet excitons. These triplets undergo triplet energy transfer to the PbS CQD layer, enhancing photocurrent generation. Owing to these synergistic effects, CQD photovoltaics (PVs) incorporating ACA-treated ZnO ETLs exhibit enhanced open-circuit voltage and short-circuit current density, resulting in a higher power conversion efficiency of 11.55% compared to 10.48% for control devices. This strategy highlights the combined advantages of electronic defect passivation and triplet exciton harvesting in PbS CQD PVs.