Improvement of Environment and Mechanical Behaviour of Filling Material of Phosphate Solid Waste Using Natural Fibre

To enhance both the environmental performance and mechanical properties of phosphate solid waste backfill materials, this study examines the effects of corn straw fibre (CS), rice straw fibre (RS), and jute fibre (JF), each at five lengths (3-15 mm) and five dosages (0.1-0.5 wt%), on the rheological behaviour, mechanical strength, and microstructural characteristics of the backfill slurry. The experimental results showed that the incorporation of natural fibres markedly improved both the compressive and tensile strengths of backfill materials. For example, incorporating CS at a length of 12 mm and a dosage of 0.2 wt% increased the compressive and tensile strengths by 144.4% and 18.8%, respectively. Likewise, RS at 3 mm and 0.2 wt% increased the strengths by 68.3% and 11.9%, while JF at 12 mm and 0.5 wt% enhanced them by 108.2% and 14.9%, respectively. Ion leaching experiments and XPS analyses confirmed that the incorporation of natural fibres effectively adsorbed and immobilized phosphorus and fluorine in phosphogypsum. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses revealed that the improved mechanical strength was primarily attributed to fibre-bridging effects and enhanced fibre-matrix bonding. Furthermore, nuclear magnetic resonance (NMR) analysis demonstrated that incorporating natural fibres reduced the porosity of backfill materials (from 12.9% to 8.14%) while increasing their density. This study provides an experimental foundation for optimizing backfill materials and recommends a 12 mm CS fibre length at a dosage of 0.2 wt% to improve the stability and safety of mine fill structures.