Carbon Quantum Dot-Embedded SiO2: PMMA Hybrid as a Blue-Emitting Plastic Scintillator for Cosmic Ray Detection

This work reports the synthesis and characterization of Carbon Quantum Dots (CQDs) embedded in an organic–inorganic hybrid SiO2: PMMA matrix, designed as a novel plastic scintillator material. The CQDs were synthesized through a solvo-hydrothermal method and incorporated using a sol–gel polymerization process, resulting in a mechanically durable and optically active hybrid. Structural analysis with X-ray diffraction and TEM confirmed crystalline quantum dots approximately 10 nm in size. Extensive optical characterization, including band gap measurement, photoluminescence under 325 nm UV excitation, lifetime evaluations, and quantum yield measurement, revealed a blue emission centered at 426 nm with a decay time of 3–3.6 ns. The hybrid scintillator was integrated into a compact cosmic ray detector using a photomultiplier tube optimized for 420 nm detection. The system effectively detected secondary atmospheric muons produced by low-energy cosmic rays, validated through the vertical equivalent muon (VEM) technique. These findings highlight the potential of CQD-based hybrid materials for advanced optical sensing and scintillation applications in complex environments, supporting the development of compact and sensitive detection systems.