Divergent synthesis of two polycyclic frameworks containing tricyclic bridgehead carbon centers by gold-catalyzed cycloisomerization of <i>o</i> -cyclopropylidenemethyl- <i>o</i> ′-alkynylbiaryls
Divergent gold-catalyzed cycloisomerizations of o -cyclopropylidenemethyl- o ′-alkynylbiaryls give access to two distinct polycyclic scaffolds containing a tricyclic bridgehead carbon center, with selectivity controlled by temperature.
Authors
- Patricia García‐García (ORCID: https://orcid.org/0000-0003-3671-5828)
- Manuel A. Fernández‐Rodríguez (ORCID: https://orcid.org/0000-0002-0120-5599)
- Luis Sánchez (ORCID: https://orcid.org/0000-0003-0156-9082)
- Adrián Gargantiel
Institutions
- Universidad de Alcalá (ES)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00816f
- Citations
- 1
- Primary Topic
- Catalytic Alkyne Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.94
Funders
- Ministerio de Ciencia, Innovación y Universidades
- European Commission
- Ministerio de Ciencia e Innovación
- Universidad de Alcalá
- Instituto de Salud Carlos III
- Agencia Estatal de Investigación