Surface sensitive catalytic mechanism of morphology and facet controlled α-MnO<sub>2</sub> nanostructures in the decomposition of ammonium perchlorate

α-MnO 2 nanocubes with (211) facets enhanced ammonium perchlorate decomposition by promoting ClO 4 − reduction, facilitated by Mn 4+ /Mn 3+ redox pairs and oxygen vacancies, shifting the pathway toward increased NO 2 evolution over N 2 O.

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Publication Details

Journal
CrystEngComm
Published
2025-01-01
DOI
https://doi.org/10.1039/d5ce00732a
Citations
2
Primary Topic
Chemical Analysis and Environmental Impact
Type
article
Field-Weighted Citation Impact
2.40
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article

Surface sensitive catalytic mechanism of morphology and facet controlled α-MnO2 nanostructures in the decomposition of ammonium perchlorate

Anuj A. Vargeese, Santra Merin Saju
2 citations
CrystEngComm
Chemical Analysis and Environmental Impact
2.40
article

Surface sensitive catalytic mechanism of morphology and facet controlled α-MnO2 nanostructures in the decomposition of ammonium perchlorate

Anuj A. Vargeese, Santra Merin Saju
article en
2 citations

Abstract

α-MnO 2 nanocubes with (211) facets enhanced ammonium perchlorate decomposition by promoting ClO 4 − reduction, facilitated by Mn 4+ /Mn 3+ redox pairs and oxygen vacancies, shifting the pathway toward increased NO 2 evolution over N 2 O.

CrystEngCommVol. 27(37)
National Institute of Technology Calicut (IN)
Openalex Percentile: Top 11%
Chemical Analysis and Environmental Impact
2.40
DOIOpen Access PDFOpenAlex
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Surface sensitive catalytic mechanism of morphology and facet controlled α-MnO<sub>2</sub> nanostructures in the decomposition of ammonium perchlorate — Anuj A. Vargeese, Santra Merin Saju · CrystEngComm (2025) | TGRS Research Map | TGRS