Carbon–Carbon/Heteroatom‐Centered Diradical Mediated Synthesis of Valuable Cyclic Motifs by EnT Catalyzed HAT Cyclization

Abstract Energy transfer (EnT) catalysis has emerged as a powerful and unique tool in modern synthetic methodology, enabling the generation of carbon–carbon/heteroatom centered diradicals from judiciously designed substrates. This highlight offers insights into recent breakthroughs including intramolecular cyclization, underscoring their potential to construct structurally complex, and valuable molecular architectures.