High Performance Energy Storage Materials Based on Rochelle Salt Micro-Doped Composite Films

Polymer dielectric materials are widely applied in next-generation capacitive energy storage systems due to their low dielectric loss, ease of processing, and excellent chemical stability. However, their generally low dielectric constant and limited charge regulation capability constrain further improvement in energy density. In this study, a flexible nanocomposite dielectric film with enhanced dielectric and energy storage properties was developed by introducing trace amounts of Rochelle salt (RS) into polypropylene (PP) through melt blending. The strong polarization and charge trapping effects of RS significantly suppressed carrier migration, reducing leakage current by 38.19 % and improving breakdown strength at various temperatures. Experimental results showed that the energy density of the composite film increased by approximately 25 % and 28 % at 25° C and <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$85^{\circ} \mathrm{C}$</tex> compared with unmodified PP, demonstrating excellent thermal stability. This approach provides a new strategy for designing highperformance dielectric materials with promising potential for next-generation electrostatic energy storage systems.

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Published
2025-08-03
DOI
https://doi.org/10.1109/icempe66159.2025.11123002
Primary Topic
Supercapacitor Materials and Fabrication
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article
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article

High Performance Energy Storage Materials Based on Rochelle Salt Micro-Doped Composite Films

Boxue X. Du, Meng Xiao, Zening Lu
Supercapacitor Materials and Fabrication
article

High Performance Energy Storage Materials Based on Rochelle Salt Micro-Doped Composite Films

Boxue X. Du, Meng Xiao, Zening Lu
article en

Abstract

Polymer dielectric materials are widely applied in next-generation capacitive energy storage systems due to their low dielectric loss, ease of processing, and excellent chemical stability. However, their generally low dielectric constant and limited charge regulation capability constrain further improvement in energy density. In this study, a flexible nanocomposite dielectric film with enhanced dielectric and energy storage properties was developed by introducing trace amounts of Rochelle salt (RS) into polypropylene (PP) through melt blending. The strong polarization and charge trapping effects of RS significantly suppressed carrier migration, reducing leakage current by 38.19 % and improving breakdown strength at various temperatures. Experimental results showed that the energy density of the composite film increased by approximately 25 % and 28 % at 25° C and <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$85^{\circ} \mathrm{C}$</tex> compared with unmodified PP, demonstrating excellent thermal stability. This approach provides a new strategy for designing highperformance dielectric materials with promising potential for next-generation electrostatic energy storage systems.

Tianjin University (CN)
National Natural Science Foundation of China
Affordable and clean energy
Openalex Percentile: Top 86%
Supercapacitor Materials and Fabrication
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High Performance Energy Storage Materials Based on Rochelle Salt Micro-Doped Composite Films — Boxue X. Du, Meng Xiao, et al. · (2025) | TGRS Research Map | TGRS