Fluorine Plasma Functionalization of Borophene Nanoflakes

Theoretical studies have indicated that borophene is a promising two-dimensional material characterized by remarkable chemical, mechanical, and electrical properties. Nonetheless, its practical applications in areas such as catalysis and gas sensing are hindered by the limited density of reactive sites in its pristine form. To address this limitation, the present study explores the controlled fluorination of borophene nanoflakes as a strategy to modify their surface chemistry and enhance the availability of active sites. Furthermore, it is anticipated that surface fluorination will improve hydrophobicity, which is crucial for reducing humidity-related interference in sensing applications. In this study, we report the successful functionalization of borophene nanoflakes with fluorine using a plasma arc discharge technique for the first time. Borophene nanolayers were synthesized via a sonochemical-assisted exfoliation method, yielding nanosheets with an average lateral dimension of approximately 100 nm. The fluorinated samples were characterized using X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and high-resolution transmission electron microscopy (HRTEM). A systematic investigation of plasma exposure durations demonstrated that fluorine was effectively introduced as a dopant while maintaining the crystallinity of the borophene lattice.