Richardson–Gaudin states of non-zero seniority. II. Single-reference treatment of strong correlation

Strongly correlated systems are well described as a configuration interaction of Slater determinants classified by their number of unpaired electrons. This treatment is, however, unfeasible. In this paper, it is demonstrated that single reference methods built from Richardson-Gaudin states yield comparable results at polynomial cost.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2025-08-22
DOI
https://doi.org/10.1063/5.0284864
Citations
3
Primary Topic
Quantum Information and Cryptography
Type
article
Field-Weighted Citation Impact
7.44

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article

Richardson–Gaudin states of non-zero seniority. II. Single-reference treatment of strong correlation

Paul A. Johnson
3 citations
The Journal of Chemical Physics
Quantum Information and Cryptography
7.44
article

Richardson–Gaudin states of non-zero seniority. II. Single-reference treatment of strong correlation

Paul A. Johnson
article en
3 citations

Abstract

Strongly correlated systems are well described as a configuration interaction of Slater determinants classified by their number of unpaired electrons. This treatment is, however, unfeasible. In this paper, it is demonstrated that single reference methods built from Richardson-Gaudin states yield comparable results at polynomial cost.

The Journal of Chemical PhysicsVol. 163(8)
Université Laval (CA)
Alliance de recherche numérique du Canada, Natural Sciences and Engineering Research Council of Canada
Openalex Percentile: Top 3%
Quantum Information and Cryptography
7.44
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