Strain and Kinetics Synergy in Octahedral High‐Entropy Cathodes Enables Ultra‐Durable Sodium‐Ion Batteries

High-entropy oxides represent a paradigm shift in sodium-ion battery cathodes by utilizing entropy-driven structural stabilization to address the intrinsic challenges of lattice strain and sluggish ion kinetics. However, conventional high-entropy oxides face challenges in synthesis complexity and insufficient mechanistic insights into strain-kinetics coupling. Here, a high-entropy O3-type layered oxide, Na_0.9Ni_0.2Co_0.2Fe_0.2Mn_0.2Zn_0.05Cu_0.05Ti_0.1O₂ (NNCFMZCT), is proposed featuring seven transition metals in a single crystallographic site, to synergistically optimize Na⁺ diffusion and structural resilience. Density functional theory calculations reveal that configurational disorder mitigates anisotropic lattice contraction during O/P phase transitions, while X-ray photoelectron spectroscopy and in situ X-ray diffraction confirm stable TMO₆ octahedra and suppressed irreversible phase transitions. The NNCFMZCT cathode delivers a high reversible capacity (>130 mAh g^-1 at 10 mA g^-1), exceptional cycling stability (82.9% retention over 300 cycles at 500 mA g^-1), and superior rate capability (>110 mAh g^-1 at 1000 mA g^-1) within 2.0-4.0 V. When paired with commercial hard carbon in ampere-hour-level cylindrical cells, the full cell achieves 84% capacity retention after 200 cycles. This work demonstrates scalable viability for grid storage by establishing a universal strain-kinetics coupling strategy, which advances the rational design of entropy-stabilized cathodes for sustainable energy systems.