5-((3′,5′-Dibromo-[2,2′-bithiophen]-5-yl)methyl)-3-ethyl-2-thioxothiazolidin-4-one∙Br2 (1:1)
The reaction of rhodanine vinyl bithiophene (BTR) with molecular dibromine (Br2) resulted in the formation of compound 1. Single-crystal X-ray diffraction analysis revealed bromination of the terminal thiophenyl ring and the formation of a 1:1 CT “spoke” adduct between the rhodanine thiocarbonyl group and a neutral dibromine (Br2) molecule.
Authors
- Anna Pintus (ORCID: https://orcid.org/0000-0001-6069-9771)
- Giuseppe Sforazzini (ORCID: https://orcid.org/0000-0002-5621-2841)
- Vito Lippolis (ORCID: https://orcid.org/0000-0001-8093-576X)
- M. Carla Aragoni (ORCID: https://orcid.org/0000-0002-5010-7370)
- Massimiliano Arca (ORCID: https://orcid.org/0000-0002-0058-6406)
- Enrico Podda (ORCID: https://orcid.org/0000-0002-4329-7751)
- Simone Acca
Institutions
- University of Cagliari (IT)
- Istituto Nazionale di Fisica Nucleare, Sezione di Cagliari (IT)
Publication Details
- Journal
- Molbank
- Published
- 2025-08-14
- DOI
- https://doi.org/10.3390/m2047
- Primary Topic
- Synthesis and Characterization of Heterocyclic Compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Università degli Studi di Cagliari
- Fondazione di Sardegna