Vertical Profiling of PM1 and PM2.5 Dynamics: UAV-Based Observations in Seasonal Urban Atmosphere

Urban particulate matter (PM) pollution critically impacts public health and climate. However, traditional ground-based monitoring fails to resolve vertical PM distribution, limiting understanding of transport and stratification-coupled mechanisms. Vertical profiles collected by an unmanned aerial vehicle (UAV) over Hangzhou, a core megacity in China’s Yangtze River Delta, reveal the spatiotemporal heterogeneity and multi-scale drivers of regional PM pollution during two intensive ten-day campaigns capturing peak pollution scenarios (winter: 17–26 January 2019; summer: 21–30 August 2019). Results show stark seasonal differences: winter PM1 and PM2.5 averages were 2.6- and 2.7-fold higher (p < 0.0001) than summer. Diurnal patterns were bimodal in winter and unimodal (single valley) in summer. Vertically consistent PM1 and PM2.5 distributions featured sharp morning (08:00) concentration increases within specific layers (winter: 250–325 m; summer: 350–425 m). Analysis demonstrates multi-scale coupling of synoptic systems, boundary layer processes, and vertical wind structure governing pollution. Key mechanisms include a winter “Transport-Accumulation-Reactivation” cycle driven by cold air, and summer typhoon circulation influences. We identify hygroscopic growth triggered by inversion-high humidity coupling and sea-breeze-driven secondary aerosol formation. Leveraging UAV-based vertical profiling over Hangzhou, this study pioneers a three-dimensional dissection of layer-coupled PM dynamics in the Yangtze River Delta, offering a scalable paradigm for aerial–ground networks to achieve precision stratified control strategies in megacities.