Outside Back Cover: Hinge‐Like Mechanochromic Mechanophores Based on [2.2]Paracyclophane (Angew. Chem. 37/2025)
Mechanochromic mechanophores function as force-reporting molecules in polymer materials. In their Research Article (e202510114), Yoshimitsu Sagara et al. demonstrate the first hinge-like mechanophore based on [2.2]paracyclophane. Polyurethane films covalently incorporating the mechanophore exhibit excimer-dominant emission in the force-free state. Upon mechanical activation, force-induced separation of the associated fluorophores leads to a change in fluorescence color from excimer-dominant bright yellow to monomer-dominant blue-green.
Authors
- Yoshimitsu Sagara (ORCID: https://orcid.org/0000-0003-2502-3041)
- Christoph Weder (ORCID: https://orcid.org/0000-0001-7183-1790)
- Shohei Shimizu (ORCID: https://orcid.org/0000-0002-1931-0733)
- Jess M. Clough (ORCID: https://orcid.org/0000-0003-3701-7829)
Institutions
- Tokyo Institute of Technology (JP)
- University of Fribourg (CH)
- Adolphe Merkle Institute (CH)
Publication Details
- Journal
- Angewandte Chemie
- Published
- 2025-08-21
- DOI
- https://doi.org/10.1002/ange.202517347
- Primary Topic
- Force Microscopy Techniques and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00