Mixed Planewave and Localized Orbital Basis for Sparse-Stochastic Hybrid Time-Dependent Density Functional Theory

We present a mixed basis-set approach to obtain optical absorption spectra within a generalized Kohn-Sham time-dependent density functional theory framework. All occupied valence molecular orbitals (MOs) are expanded in a plane-wave (PW) basis, while unoccupied MOs are derived primarily from localized atomic basis functions. The method accelerates spectral convergence when compared to fully PW-based simulations, with a 2-3 fold reduction in the number of unoccupied MOs entering the Casida equation. The mixed-basis is placed on a common real-space grid, enabling our previously developed deterministic/sparse-stochastic evaluation of the exact exchange operator (<i>J. Chem. Theory Comput.</i> <b>2023,</b> <i>19,</i> 9239-9247). This chemically intuitive and computationally efficient approach is validated across various molecular systems, including π-conjugated polymethine dyes, aromatic hydrocarbons, and a chlorophyll monomer.