<i>N</i>-(4-Amino-1,2,5-oxadiazol-3-yl)formamide

The asymmetric unit of the title compound, C<sub>3</sub>H<sub>4</sub>N<sub>4</sub>O<sub>2</sub>, contains two coplanar mol-ecules (<i>A</i> and <i>B</i>) completely located on mirror planes. In the crystal, N-H⋯O, N-H⋯N, C-H⋯O and C-H⋯N hydrogen bonds link the mol-ecules into sheets parallel to (010). There are neither significant π-π nor C-H⋯π(ring) inter-actions. Hirshfeld surface analysis indicates that the most important contributions to the crystal packings of mol-ecules <i>A</i> and <i>B</i> are from H⋯O/O⋯H (32.4% for <i>A</i>, 30.1% for <i>B</i>), H⋯N/N⋯H (28.2%, 31.5%) and H⋯H (12.3%, 8.0%) inter-actions.

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IUCrData
Published
2025-08-13
DOI
https://doi.org/10.1107/s2414314625007205
Primary Topic
Synthesis and biological activity
Type
article
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article

N-(4-Amino-1,2,5-oxadiazol-3-yl)formamide

Mohammed Hadi Al–Douh, Aida I. Samigullina, Tuncer Hökelek, Е. В. Шувалова et al.
IUCrData
Synthesis and biological activity
article

N-(4-Amino-1,2,5-oxadiazol-3-yl)formamide

Mohammed Hadi Al–Douh, Aida I. Samigullina, Tuncer Hökelek, Е. В. Шувалова, Firudin I. Guseinov, Khudayar I. Hasanov, Nizami A. Ekberov
article en

Abstract

The asymmetric unit of the title compound, C<sub>3</sub>H<sub>4</sub>N<sub>4</sub>O<sub>2</sub>, contains two coplanar mol-ecules (<i>A</i> and <i>B</i>) completely located on mirror planes. In the crystal, N-H⋯O, N-H⋯N, C-H⋯O and C-H⋯N hydrogen bonds link the mol-ecules into sheets parallel to (010). There are neither significant π-π nor C-H⋯π(ring) inter-actions. Hirshfeld surface analysis indicates that the most important contributions to the crystal packings of mol-ecules <i>A</i> and <i>B</i> are from H⋯O/O⋯H (32.4% for <i>A</i>, 30.1% for <i>B</i>), H⋯N/N⋯H (28.2%, 31.5%) and H⋯H (12.3%, 8.0%) inter-actions.

IUCrDataVol. 10(8)
A. N. Kosygin Moscow State Textile University (RU), Azerbaijan Medical University (AZ), Hadhramout University (YE), N.D. Zelinsky Institute of Organic Chemistry (RU), Azerbaijan State Pedagogical University (AZ), Hacettepe University (TR)
Openalex Percentile: Top 84%
Synthesis and biological activity
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