Enaminone-Directed Rh(III)-Catalyzed Hydroarylation Reaction of Oxa/azabenzonorbornadienes through C–H Bond Functionalization

Abstract We report an Rh(III)-catalyzed hydroarylation of oxa- and azabenzonorbornadienes directed by enaminones through C–H activation. The reaction proceeds under mild conditions with broad substrate scope and excellent regioselectivity. Diverse polycyclic products are obtained in high yields. A representative structure was confirmed by X-ray analysis.

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Publication Details

Journal
Synlett
Published
2025-08-19
DOI
https://doi.org/10.1055/a-2685-9449
Citations
1
Primary Topic
Catalytic C–H Functionalization Methods
Type
article
Field-Weighted Citation Impact
0.94
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article

Enaminone-Directed Rh(III)-Catalyzed Hydroarylation Reaction of Oxa/azabenzonorbornadienes through C–H Bond Functionalization

Jitendra D. Belani, Milind M. Ahire
1 citations
Synlett
Catalytic C–H Functionalization Methods
0.94
article

Enaminone-Directed Rh(III)-Catalyzed Hydroarylation Reaction of Oxa/azabenzonorbornadienes through C–H Bond Functionalization

Jitendra D. Belani, Milind M. Ahire
article en
1 citations

Abstract

Abstract We report an Rh(III)-catalyzed hydroarylation of oxa- and azabenzonorbornadienes directed by enaminones through C–H activation. The reaction proceeds under mild conditions with broad substrate scope and excellent regioselectivity. Diverse polycyclic products are obtained in high yields. A representative structure was confirmed by X-ray analysis.

SynlettVol. 37(01)
Thomas Jefferson University (US)
Openalex Percentile: Top 23%
Catalytic C–H Functionalization Methods
0.94
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Enaminone-Directed Rh(III)-Catalyzed Hydroarylation Reaction of Oxa/azabenzonorbornadienes through C–H Bond Functionalization — Jitendra D. Belani, Milind M. Ahire · Synlett (2025) | TGRS Research Map | TGRS