On Some Features of the Interaction of Ultrasmall Gold Nanoparticles with Liquid-Crystalline DNA Microparticles

The features of the interaction of ultrasmall gold nanoparticles (GNPs) synthesized via Duff method with particles of optically active liquid-crystalline dispersions (LCDs) of DNA formed at varying concentrations of NaCl and polyethylene glycol were studied. It was shown that the GNPs have different effects on the LCDs with positive and negative orientation of anomalous circular dichroism (CD) signal. Apparently, this is in a measure due to the various conformation of the DNA molecules that form the corresponding dispersed particles. The kinetic aspects of the interaction of GNPs with DNA LCDs and the features of “loading” ultradispersed gold into the LCD particles are also discussed.

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Publication Details

Journal
Colloid Journal
Published
2025-08-18
DOI
https://doi.org/10.1134/s1061933x25600289
Primary Topic
Gold and Silver Nanoparticles Synthesis and Applications
Type
article
Field-Weighted Citation Impact
0.00
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article

On Some Features of the Interaction of Ultrasmall Gold Nanoparticles with Liquid-Crystalline DNA Microparticles

О. В. Дементьева, Anna V. Shibaeva, В. Н. Морозов, V. A. Kuz’min et al.
Colloid Journal
Gold and Silver Nanoparticles Synthesis and Applications
article

On Some Features of the Interaction of Ultrasmall Gold Nanoparticles with Liquid-Crystalline DNA Microparticles

О. В. Дементьева, Anna V. Shibaeva, В. Н. Морозов, V. A. Kuz’min, М. А. Колыванова, V. M. Rudoy, M. A. Klimovich
article en

Abstract

The features of the interaction of ultrasmall gold nanoparticles (GNPs) synthesized via Duff method with particles of optically active liquid-crystalline dispersions (LCDs) of DNA formed at varying concentrations of NaCl and polyethylene glycol were studied. It was shown that the GNPs have different effects on the LCDs with positive and negative orientation of anomalous circular dichroism (CD) signal. Apparently, this is in a measure due to the various conformation of the DNA molecules that form the corresponding dispersed particles. The kinetic aspects of the interaction of GNPs with DNA LCDs and the features of “loading” ultradispersed gold into the LCD particles are also discussed.

Colloid JournalVol. 87(5)
Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (RU), Institute of Biochemical Physics NM Emanuel (RU), Federal Medical-Biological Agency (RU)
Openalex Percentile: Top 87%
Gold and Silver Nanoparticles Synthesis and Applications
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