Improving the Environmental Friendliness of Graphite Oxidation Technology

It is noted that at obtaining 1 kg of oxidised graphite by dichromate technology, 180.21 thousand litres of waste water containing 1394.11 kg of sulphate ions and 224.11 kg of total chromium are generated. The technology of graphite oxidation is proposed, which consists in the fact that at the stage of oxidising mixture dilution waste water with pH = 0÷1 (very acidic) from the previous graphite oxidation process, containing the highest concentrations of sulphate ions and total chromium, was used. To produce 1 tonne of oxidised graphite using this technology, 176.7 thousand litres of waste water containing 1349.15 kg of sulphate ions and 223.06 kg of total chromium were discharged to the sludge fields. It was found that the composition of waste water (in terms of sulphate ions and total chromium) remains practically constant when its volume is reduced by 6.5 thousand litres. It is concluded that graphite oxidation using waste water reduces the ecological load on the environment.

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Publication Details

Journal
Ecology and Industry of Russia
Published
2025-08-12
DOI
https://doi.org/10.18412/1816-0395-2025-8-8-12
Primary Topic
Recycling and Waste Management Techniques
Type
article
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article

Improving the Environmental Friendliness of Graphite Oxidation Technology

T. R. Gilmanshina, Татьяна Валерьевна Твердохлебова, G. A. Koroleva, И. В. Дубова et al.
5 links
Ecology and Industry of Russia
Recycling and Waste Management Techniques
article

Improving the Environmental Friendliness of Graphite Oxidation Technology

T. R. Gilmanshina, Татьяна Валерьевна Твердохлебова, G. A. Koroleva, И. В. Дубова, M. Yu. Olshevsky
article en

Abstract

It is noted that at obtaining 1 kg of oxidised graphite by dichromate technology, 180.21 thousand litres of waste water containing 1394.11 kg of sulphate ions and 224.11 kg of total chromium are generated. The technology of graphite oxidation is proposed, which consists in the fact that at the stage of oxidising mixture dilution waste water with pH = 0÷1 (very acidic) from the previous graphite oxidation process, containing the highest concentrations of sulphate ions and total chromium, was used. To produce 1 tonne of oxidised graphite using this technology, 176.7 thousand litres of waste water containing 1349.15 kg of sulphate ions and 223.06 kg of total chromium were discharged to the sludge fields. It was found that the composition of waste water (in terms of sulphate ions and total chromium) remains practically constant when its volume is reduced by 6.5 thousand litres. It is concluded that graphite oxidation using waste water reduces the ecological load on the environment.

Ecology and Industry of RussiaVol. 29(8)
University of Antique (PH), Siberian Federal University (RU)
Openalex Percentile: Top 74%
Recycling and Waste Management Techniques
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