WSe2 nanoflowers grown on Ti3C2Cl2 MXene for energy applications and sensing

Abstract Developing multifunctional materials for energy and sensing is challenging due to demands for high conductivity, catalytic activity, and structural stability. We report a WSe 2 /Ti 3 C 2 Cl 2 hybrid synthesized via one-step solvothermal growth of WSe 2 nanoflowers on Cl-terminated MXene. The strong interface improves electron transport and active site exposure, achieving excellent hydrogen evolution activity with an overpotential of −0.19 V vs RHE at −10 mA cm −2 . The WSe 2 -rich hybrid delivers an initial discharge capacity of 1255 mAh g −1 as a lithium-ion battery anode, outperforming its individual components. MXene boosts conductivity, while WSe 2 morphology buffers volume changes. For sensing, the hybrid doubles the H 2 O 2 reduction signal of WSe 2 and enables amperometric detection from 1 to 88 μM with a 0.6 μM detection limit. Overall, in situ growth of WSe 2 on MXene offers a scalable route to efficient multifunctional materials.