Optimizing Interfacial Adhesion and Mechanical Performance of Multimaterial Joints Fabricated by Material Extrusion

Multimaterial 3D printing is transforming the landscape of additive manufacturing, enabling the production of advanced, functional parts with tailored properties for sectors like automotive, aerospace, and engineering. However, achieving strong interlayer adhesion between different polymers remains a significant challenge, limiting the mechanical reliability. This study investigates adhesion properties of widely used materials-polycarbonate (PC), acrylonitrile styrene acrylate (ASA), polylactic acid (PLA), and polyethylene terephthalate glycol (PETG)-and enhances mechanical performance of structural joints through optimized interlayer bonding techniques. Using the Material Extrusion (MEX) method, tensile testing was employed to evaluate the mechanical strength of joints by co-depositing and bonding material layers during the printing process. The results demonstrate that specific material combinations and joint design strategies, particularly increasing the interfacial contact area and applying interlayer bonding pressure, significantly enhance tensile strength. For instance, the strength of PC/PTEG composite joints increased from 15.2 MPa (standard joint) to 29.9 MPa (interlayer bonding strategy), nearly doubling the bond strength. These findings provide valuable insights into the behavior of multimaterial joints and propose practical approaches for improving the durability and functionality of 3D-printed structures. This research lays the groundwork for advancing multimaterial additive manufacturing, with implications for high-performance applications in engineering, aerospace, and beyond.