Visible light promoted oxygenation of oxazolidinones by an anthraquinone-resorcinol based donor–acceptor polymer as a heterogeneous photocatalyst
The direct conversion of 2-oxazolidinone to oxazolidine-2,4-dione can be achieved by C(sp<sup>3</sup>)-H bond activation using a heterogeneous photocatalyst. Here, a donor-acceptor (D-A) conjugated heterogeneous polymer (ACP) was employed as an efficient photocatalyst for the oxidation. Upon light irradiation, ACP functions as a photo-base and facilitates the reaction <i>via</i> a proton-coupled electron transfer (PCET) mechanism.
Authors
- Shiladitya Roy
- Sanjio S. Zade (ORCID: https://orcid.org/0000-0001-8902-257X)
- Ajay V. Munde (ORCID: https://orcid.org/0000-0002-4933-4904)
- Devendra Mayurdhwaj Sanke (ORCID: https://orcid.org/0000-0002-7254-1012)
Institutions
- Indian Institute of Science Education and Research Kolkata (IN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc03245h
- Citations
- 1
- Primary Topic
- Chemical Synthesis and Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.94