Diastereospecific cyclization of 3-arylidene-1-pyrrolinium salts containing an alkyltriarylphosphonium fragment: a path to the synthesis of new pyrrolizidine derivatives

We report a diastereospecific method for the synthesis of phosphorus-containing pyrrolizidines based on the cyclization of 3-arylidene-1-pyrrolinium containing an alkyltriphenylphosphonium salt fragment catalyzed by sodium ethylate and water.

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Publication Details

Journal
New Journal of Chemistry
Published
2025-01-01
DOI
https://doi.org/10.1039/d5nj02552d
Primary Topic
Phosphorus compounds and reactions
Type
article
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article

Diastereospecific cyclization of 3-arylidene-1-pyrrolinium salts containing an alkyltriarylphosphonium fragment: a path to the synthesis of new pyrrolizidine derivatives

Anna P. Lyubina, M. A. Pudovik, Аndrey V. Smolobochkin, Tanzilya S. Rizbayeva et al.
New Journal of Chemistry
Phosphorus compounds and reactions
article

Diastereospecific cyclization of 3-arylidene-1-pyrrolinium salts containing an alkyltriarylphosphonium fragment: a path to the synthesis of new pyrrolizidine derivatives

Anna P. Lyubina, M. A. Pudovik, Аndrey V. Smolobochkin, Tanzilya S. Rizbayeva, А. Р. Бурилов, Almir S. Gazizov, Аnastasiia S. Sapunova, Alexandra D. Voloshina, Olga B. Babaeva, D. P. Gerasimova
article en

Abstract

We report a diastereospecific method for the synthesis of phosphorus-containing pyrrolizidines based on the cyclization of 3-arylidene-1-pyrrolinium containing an alkyltriphenylphosphonium salt fragment catalyzed by sodium ethylate and water.

New Journal of ChemistryVol. 49(34)
A.E. Arbuzov Institute of Organic and Physical Chemistry (RU)
Clean water and sanitation
Openalex Percentile: Top 84%
Phosphorus compounds and reactions
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Diastereospecific cyclization of 3-arylidene-1-pyrrolinium salts containing an alkyltriarylphosphonium fragment: a path to the synthesis of new pyrrolizidine derivatives — Anna P. Lyubina, M. A. Pudovik, et al. · New Journal of Chemistry (2025) | TGRS Research Map | TGRS